Critical metal enrichment in coal-bearing strata of the eastern Ordos Basin: A geophysical and geochemical study
Coal-bearing strata hold significant potential for critical metal resources. This study investigates their enrichment mechanisms in the eastern Ordos Basin using an integrated geophysical-geochemical approach. We combine seismic impedance inversion, tectonic evolution, and log facies interpretation with geochemical data (total organic carbon, sulfur, vitrinite reflectance, trace/rare earth elements) to reconstruct the sedimentary-tectonic-hydrogeological evolution. Results show notable enrichment of zirconium, chromium (Cr), nickel, and hafnium. Seismic facies indicate that deltaic distributary channels and tidal sandbars were primary conduits for metal-bearing fluids. The Taiyuan Formation was deposited in a warm-humid, freshwater-influenced tidal delta-barrier island system under reducing conditions, enabling initial metal sequestration via sulfidation and organic complexation. Reconstruction of tectonic evolution confirms that Yanshanian tectono-thermal events associated with the Zijinshan pluton generated fault networks that channeled hydrothermal fluids, driving secondary metal enrichment. Groundwater circulation, controlled by sedimentary facies and fractures, further regulates metal remobilization. A focused study on Cr delineates a three-stage enrichment model: source weathering, sedimentary reduction, and tectonic-hydrothermal activation. This work establishes a structure–sedimentation–groundwater coupled joint ore-controlling model, underscoring the value of integrated geophysical and geochemical methods for exploring critical metals in coal-bearing strata.
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